Hydroxyphthioceranic acid
WebFor example, incorporating sequential lithiation–borylation and Matteson homologation steps (see Section 4.1) followed by Morken's amination protocol (see Section 2.2) afforded 89 in 52% yield , an intermediate in the synthesis of (+)-kalkitoxin (90). 59 Sequential homologations were also utilised in the synthesis of (+)-hydroxyphthioceranic acid (92) … WebLM ID: LMFA01020325: Common Name: Hydroxyphthioceranic acid (C39) Systematic Name: 2S,4S,6S,8S,10R,12R,14R-heptamethyl-15-hydroxy-dotriacontanoic acid
Hydroxyphthioceranic acid
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http://www.chm.bris.ac.uk/org/aggarwal/docs/publications/227pub.pdf Web14 jul. 2007 · The first total synthesis of phthioceranic acid (1) has been achieved by an iterative catalytic asymmetric 1,4-addition protocol. This method provides a robust and …
WebSatoshi Yuzawa, ...Jay D. Keasling, in Methods in Enzymology, 2024 3.3 Computer-Aided Design. PKS engineering could be greatly aided by computational tools. Huge amounts of information have accumulated since the discovery of modular PKSs, and several PKS-related databases were developed to store and utilize this information for specific … WebThis mycobacterial polyketide enzyme produces the hepta- and octa-methylated fatty acids known as phthioceranic acids, and presumably their hydroxylated versions. Formation of …
WebBRENDA Home spontaneous reaction (0.0.0.0) alcohol dehydrogenase (1.1.1.1) alcohol dehydrogenase (NADP+) (1.1.1.2) (S)-specific secondary alcohol dehydrogenase (1.1.1.B3) homoserine dehydrogenase (1.1.1.3) (R)-specific secondary alcohol dehydrogenase (NADH) (1.1.1.B4) (R,R)-butanediol dehydrogenase (1.1.1.4) acetoin dehydrogenase … WebWe employed this strategy in the synthesis of hydroxyphthioceranic acid, a key component of the cell-wall lipid of the virulent Mycobacterium tuberculosis, in just 14 …
Web1 sep. 2007 · In the case of (+)-hydroxyphthioceranic acid, 16 iterative homologations were conducted on p-MeOC6H4Bpin with only four intermediate purifications before …
Web19 aug. 2013 · In the case of (+)-hydroxyphthioceranic acid, 16 iterative homologations were conducted on p-MeOC6H4Bpin with only four intermediate purifications before … hawaiian airlines reservations officialWebHydroxyphthioceranic acid (C43) Systematic Name 2S,4S,6S,8S,10S,12R,14R,16R,18R-nonamethyl-19-hydroxy-tetratriacontanoic acid Synonyms LM ID LMFA01020328 Status … bosch hvac systems reviewsWebhexacosanoic acid-C 3 1 H 6 2 O 3: 482.4699: Fatty Acids and Conjugates [FA01] Branched fatty acids [FA0102] LMFA01020321: Hydroxyphthioceranic acid (C33) … bosch hxr39ai50 herdWeb28 okt. 2014 · Convergence, practicality, and stereocontrol are characteristic features of a new and flexible synthesis of biologically relevant polydeoxypropionates such as the glycolipid membrane components phthioceranic acid and hydroxyphthioceranic acid (1; see scheme).Central steps of our approach include two Suzuki–Miyaura cross-coupling … hawaiian airlines reservations phoneWebThis mycobacterial polyketide enzyme produces the hepta- and octa-methylated fatty acids known as phthioceranic acids, and presumably their hydroxylated versions. Formation of … bosch hxn390d61lWebNMR Spectra of (+)-Hydroxyphthioceranic Acid 17.....93. S-2 General Information All air- and water-sensitive reactions were carried out in oven-dried glassware under a N 2 … hawaiian airlines reservations phone numbersWeb19 aug. 2013 · In the case of (+)-hydroxyphthioceranic acid, 16 iterative homologations were conducted on p-MeOC6H4Bpin with only four intermediate purifications before oxidation of the C-B bond to the desired ... hawaiian airlines reservations site